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E.I. Germer Complete text of the article:Download article (pdf, 0.4MB )UDС630*86DOI:AbstractIt is noted that metal complexes of variable valency can act as efficient catalysts for many chemical redox-processes, including oxygen-alkaline cooking (delignification) of wood. It is shown that 1.10-phenanthrolinate copper (II) is the most active catalyst of delignification accelerating the process resulting from rate constant increase up to 15 – 28 times (depending on the process conditions and type of delignification material) at charge of ligand and central ion of 0,50 and 0,05% correspondingly of the dry wood mass.AuthorsE.I. GermerAffiliationStudying Super Active Catalysis of Oxygen-alkaline Wood Delignification by Metal Groups of Variable Valency by Using 1.10-phenanthrolinate Copper (II) as Model. 1. Approach to Problem Research. 1.10-phenanthrolinate Copper (II) Performance |
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