Fraud Warning
We officially declare that NO MONEY from authors and members of the Editorial Board IS CHARGED! A big request to ignore spam e-mails.

Address: 17 Naberezhnaya Severnoy Dviny, Arkhangelsk 163002 Russian Federation. Northern (Arctic) Federal University named after M.V.Lomonosov. Office 1425

Phone / Fax: (818-2) 21-61-18
E-mail: forest@narfu.ru
http://lesnoizhurnal.ru/en/

Lesnoy Zhurnal

Peroxide-Acetate Delignification Patterns of Non-Wood Raw Material Containing

Версия для печати

D.Yu. Arsenyeva, Ya.V. Kazakov, E.O. Okulova, A.Yu. Lagunov

Complete text of the article:

Download article (pdf, 0.6MB )

UDС

676.16.022.6.034

DOI:

10.17238/issn0536-1036.2019.3.143

Annotation

The paper considers the properties of cellulose obtained from flax production wastes (shive) by peroxide-acetate method using concentrated sulfuric acid as a catalyst. Pulping of flax shive with 38.5 % of cellulose, 15 % of lignin, and 4.1 % of ash were carried out under the laboratory conditions with 1:10 hydromodulus. The catalyst consumption was 1.0, 0.5 and 0.25 % of the pulping solution volume. Chemical and structural-morphological properties of obtained samples were determined by standard methods. It has been found that the use of peroxide-acetate method of flax shive pulping using sulfuric catalyst allows to obtain a semifinished product with more than 79 % of whiteness and Kappa of 3 units in one step. The most optimal ratio of the catalyst in the pulping solution is 0.5 % by the volume to the pulping solution, which contributes to the quality improvement of flax cellulose: lignin content reducing, whiteness increasing, ash content decreasing, and mean fiber length maintaining. It is shown that reduction in catalyst consumption to 0.25 % (vol.) leads to manufacturing a product with an increased yield (40 %), reduced whiteness and α-cellulose content, which indicates the preservation of the carbohydrate complex during pulping, decrease in the short fiber fractions proportion, and increase in the long fiber proportion due to the reduced fiber damage in the process.

Authors

D.Yu. Arsenyeva, Postgraduate Student; ORCID: 0000-0002-7816-6727
Ya.V. Kazakov, Doctor of Engineering, Assoc. Prof.; ResearcherID: J-4634-2012, ORCID: 0000-0001-8505-5841
E.O. Okulova, Postgraduate Student
A.Yu. Lagunov, Candidate of Pedagog., Assoc. Prof.; ResearcherID: I-3668-2015, ORCID: 0000-0002-2914-0045

Authors job

Northern (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russian Federation; e-mail: darsenieva@ mail.ru, j.kazakov@narfu.ru, e.okulova@narfu.ru

Keywords

flax cellulose fiber, peroxide acetate method, peracetic acid, flax shive, waste recycling

For citation

Arsenyeva D.Yu., Kazakov Ya.V., Okulova E.O., Lagunov A.Yu. Peroxide-Acetate Delignification Patterns of Non-Wood Raw Material Containing Cellulose in the Presence of Sulfuric Catalyst. Lesnoy Zhurnal [Forestry Journal], 2019, no. 3, pp. 143–151. DOI: 10.17238/issn0536-1036.2019.3.143

References

1. Arsenyeva D.Yu., Zakharova AA, Artemov A.V. Features of the Peroxide Acetate Method of Obtaining Pulp from Plant Material. Estestvennyye i tekhnicheskiye nauki [Natural and Technical Sciences], 2016, no. 8, pp. 30–33.
2. Arsenyeva D.Yu., Kazakov Ya.V. Paper-Forming Properties of Fibers Obtained from Flax Straw by Peroxide Acetate Method. The Issues in Mechanics of Pulp and Paper Materials: Proc. of the IV Int. Sci.-Tech. Conf. (Arkhangelsk, September 14–16, 2017). Arkhangelsk, NArFU Publ., 2017, pp. 303–307.
3. Vershinin M.S., Garaeva M.R., Mingazova V.K. Research of Celluloses Thermal Characteristics which Was Produced from Plant Raw Materials. Privolzhskij nauchnyj vestnik, 2017, no. 3(67), pp. 10–13.
4. Volkova N.N., Obrezkova M.V., Kunichan V.A. Flax Pulp Production on the Cotton Cellulose Production Line. Polzunovskiy vestnik [Polzunovsky Vestnik], 2007, no. 3, pp. 25–27.
5. GOST 595–79. Cotton cellulose. Technical Specifications. Moscow, Standards Publ., 2002. 14 p.
6. GOST 11960–79. Fibre Semi-Products and Raw Materials of Annuals for and Pa-per Industry. Method for Determination of Lignin. Moscow, Standards Publ., 1985. 4 p.
7. GOST 5556–81. Absorbent Medical Cotton Wool. Technical Specifications. Mos-cow, Standards Publ., 1993. 13 p.
8. Glazova N.V., Satina O.I. Peracetic Acid (PAA): An Environmentally Friendly Alternative to Chlorine. Ptitsa i рtitseprodukty, 2010, no. 1, pp. 58–60.
9. Kovalenko M.V, Sibaeva A.R. Comparative Analysis of the Sorption Capacity of Larch and Pine Wood Pulp Samples. ISJ Theoretical & Applied Science, 2013, no. 12(8), pp. 31–34. DOI: 10.15863/TAS.2013.12.8.7
10. Kuznetsov B.N., Kuznetsova S.A., Danilov V.G., Yatsenkova O.V. Catalytic Methods of Processing of Wood into Pulp with Low Contents of Lignin. Tsellyuloza. Bumaga. Karton, 2007, no. 12, pp. 27–30.
11. Milovidova L.A., Kholmova M.A., Komarova G.V. Pulp Bleaching: Laboratory Operations Manual. Arkhangelsk, NArFU Publ., 2011, pp. 20–22.
12. Minakova A.R. Cellulose Production by an Oxidation and Organo-Solvent Method in the Processing of Non-Wood Plant Raw Materials: Cand. Eng. Sci. Diss. Arkhangelsk, 2008. 151 p.
13. Barbash V., Poyda V., Deykun I. Peracetic Acid Pulp from Annual Plants. Cellulose Chemistry and Technology, 2011, vol. 45, iss. 9–10, pp. 613–618.
14. Biswas A., Saha B.C., Lawton J.W., Shogren R.L., Willett J.L. Process for Obtaining Cellulose Acetate from Agricultural By-Products. Carbohydrate Polymers, 2006, vol. 64, iss. 1, pp. 134–137. DОI: 10.1016/j.carbpol.2005.11.002
15. Coletti A., Valerio A., Vismara E. Posidonia oceanica as a Renewable Lignocellulosic Biomass for the Synthesis of Cellulose Acetate and Glycidyl Methacrylate Grafted Cellulose. Materials, 2013, vol. 6(5), pp. 2043–2058. DOI: 10.3390/ma6052043
16. Jackson M., Lewis K.S., Lewis M.S., McKean W.T., Pan W.L. Final Report on Washington State Department of Ecology AG-Burning Permit Project Contract no. C030085 for Lewis Engineering Consultants. 2003. 70 p.
17. Laamanen L.A., Sundquist J.J., Wartiovaara Y.P. Menetelma valkaistun selluloosamassan valmistamiseksi ligniimpitoisesta raakaameesta. Pat. Finland no. 74750, 1988.
18. Pohjanvesi S., Saan K., Poopius-Levlin K., Sundquist J. Technical and Economical Feasibility Study of the Milox Process. Proceedings of the 8th International Symposium on Wood and Pulping Chemistry June 6–9, 1995, Helsinki, Finland. Helsinki, 1995, vol. 2, pp. 231–236.
19. Poppius K., Laamanen L., Sundquist J., Wartiovaara I., Kaulimakis A. Bleached Pulp by Peroxyacid-Alkaline Delignification. Paperi Ja Puu, 1986, vol. 68, no. 2, pp. 87–88, 90–92.
20. Poppius-Levlin K., Mustonen R., Muovila Т., Sundquist J. Milox Pulping with Acetic Acid-Peroxyacetic Acid. Paperi Ja Puu, 1991, vol. 73, no. 2, pp. 154–158.
21. Sundquist J. From Test Tube to Pilot Plant: The First Miles on the Roach of the Milox Pulping and Bleaching Method. Finn. Chem. Congr., Helsinki, November 12–14, 1991. Kemiakemi, 1991, no. 108.
22. Sundquist J. Chemical Pulping Based on Formic Acid: Summary of Milox Re-search. Paperi Ja Puu, 1996, vol. 78, no. 3, pp. 92–95.
23. Sundquist J., Laamanen L., Poppius K. Problems of Nonconventional Pulping Process in the Light of Peroxyformic Acid Cooking Experiments. Paperi Ja Puu, 1988, vol. 70, no. 2, pp. 143–148.

Received on September 07, 2018


Peroxide-Acetate Delignification Patterns of Non-Wood Raw Material Containing

 

INDEXED IN: