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N.S. Nikulina, G.Yu. Vostrikova, A.I. Dmitrenkov, O.N. Filimonova, S.S. Nikulin Complete text of the article:Download article (pdf, 0.6MB )UDС674.02+674.048.5DOI:10.17238/issn0536-1036.2016.5.167AbstractWaste and by-products formed and accumulated at the enterprises of the petrochemical industry are numerous and various in qualitative and quantitative terms. A problem solution of processing and use of this waste is inextricably linked with the protection of the environ-ment from pollution, the integrated use of raw materials. This helps to increase the produc-tivity of technological processes, a more complete and efficient use of chemical raw materi-als. Numerous wastes of petrochemical industries, which include the companies producing synthetic rubbers, contain a large number of compounds with different reaction activity. These compounds can serve as a valuable raw material for organic synthesis, and obtain polymeric materials that can be used in the manufacture of paints, composites for various purposes, impregnating compositions, etc. The paper describes the possibility of using pol-ymeric petroleum resin based on C9 fraction for the protective treatment of fibreboards. The research is carried out using the experimental design technique according to the Graeco-Latin square design of order 4. The experimental results are processed using the computing means. As a result the regression equations are derived which describe the influence of the basic technological process parameters on the properties of the fibreboard samples. The im-pregnated fiberboard by petroleum resin can improve water-repellent properties and flexural strength. The best results of fiberboards have been achieved at the temperature of impregna-tion of 80 °C, the temperature of heat treatment of 170 °C and duration of heat treatment for 5 hours. The treatment of fibreboards by modified polymeric petroleum resin can effectively protect them from the adverse effects, extend the service life of the products.AuthorsN.S. Nikulina1, Candidate of Engineering Sciences G.Yu. Vostrikova2, Candidate of Chemical Sciences, Associate Professor A.I. Dmitrenkov3, Candidate of Engineering Sciences, Associate Professor O.N. Filimonova4, Doctor of Engineering Sciences, Associate Professor S.S. Nikulin4, Doctor of Engineering Sciences, ProfessorAffiliation1Voronezh Institute of State Firefighting Service of the Ministry of the Russian Federation for Civil Defence, Emergencies and Elimination of Consequences of Natural Disasters, Krasnoznamennaya ul., 231, Voronezh, 394052, Russian Federation;e-mail: nad.nikulina2013@yandex.ru 2 Voronezh State University of Architecture and Civil Engineering, 20-letiya Oktyabrya str., 84, Voronezh, 394006, Russian Federation; e-mail: vostr76-08@live.ru 3 Voronezh State Academy of Forestry Engineering, Timiryazev str., 8, Voronezh, 394087, Russian Federation; e-mail: chem@vglta.vrn.ru 4 Voronezh State University of Engineering Technology, Revolyutsii str., 19, Voronezh, 394036, Russian Federation; e-mail: olga270757@rambler.ru, Nikulin_sergey48@mail.ru Keywordsindustrial waste, C9 hydrocarbon fraction, polymeric petroleum resin, Graeco-Latin square design of order 4, fibreboard.References1. Grachev Yu.P., Plaksin Yu.M. Matematicheskie metody planirovaniya eksperi-menta [Mathematical Experimental Design Technique]. Moscow, 2005. 296 p. 2. Dmitrenkov A.I., Filimonova O.N., Vostrikova G.Yu., Nikulin S.S. Modifikatsiya neftepolimernoy smoly iz fraktsii С9 otkhodami butadien-stirol'nogo kauchuka i ee prime-nenie dlya zashchitnoy obrabotki DVP [Modification of Polymeric Petroleum Resin Based on C9 Fraction by Styrene-Butadiene Rubber Waste and Its Use for Protective Treatment of Fiberboard]. Lesnoy zhurnal, 2013, no. 4, pp. 97–105. 3. Nikulin S.S., Dmitrenkov A.I., Butenko T.R., Sidorov S.L., Shapovalova N.N., Khokhlova O.A. Sopolimery na osnove kubovykh ostatkov rektifikatsii stirola v proizvod-stve drevesnovoloknistykh plit [Copolymers Based on Styrene Distillation Bottoms in the Production of Fiber Boards]. Lesnoy zhurnal, 1996, no. 3, pp. 82–86. 4. Nikulin S.S., Dmitrenkov A.I., Sidorov S.L., Shapovalova N.N., Khokhlova O.A. Ispol'zovanie nizkomolekulyarnykh sopolimerov iz otkhodov proizvodstva sinteticheskikh kauchukov dlya propitki drevesnovoloknistykh plit [The Use of Low Molecular Weight Copolymers Based on Industrial Waste of Synthetic Rubber for Fibreboard Impregnation]. Lesnoy zhurnal, 1996, no. 3, pp. 86–89. 5. Nikulin S.S., Shein V.S., Zlotskiy S.S., Cherkashin M.I., Rakhmankulov D.L. Ot-khody i pobochnye produkty neftekhimicheskikh proizvodstv – syr'e dlya organicheskogo sinteza [Waste and By-Products of Petrochemical Production are the Raw Materials for Or-ganic Synthesis]. Moscow, 1989. 240 p. 6. Chernaya A.N., Nikulin S.S. Modifikatsiya neftepolimernoy smoly iz fraktsii С9 vtorichnym penopolistirolom i ee primenenie dlya zashchitnoy obrabotki drevesiny [Modifi-cation of Petroleum Resin Based on C9 Fraction by the Secondary Polystyrene Foam and Its Use for the Protective Treatment of Wood]. Khimicheskaya promyshlennost' segodnya [Chemical Industry Today], 2009, no. 4, pp. 28–33. 7. Ali Sami, Muthana Mohammed, Ahmad Dhary. Synthesis of Сarbon Nanofibers from Decomposition of Liquid Organic Waste from Chemical and Petrochemical Industries. Energy Procedia, 2015, vol. 74, pp. 4–14. 8. Eyitayo Olatunde Olakanmi, Moses J. Strydom. Critical Materials and Processing Challenges Affecting the Interface and Functional Performance of Wood Polymer Compo-sites. Materials Chemistry and Physics, 2016, vol. 171, pp. 290–302. Received on March 29, 2016 C9 Polymeric Petroleum Resin is a Fibreboard Modifier |
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