Address: 17 Naberezhnaya Severnoy Dviny, Arkhangelsk 163002 Russian Federation. Northern (Arctic) Federal University named after M.V.Lomonosov. Office 1425

Phone / Fax: (818-2) 21-61-18
E-mail: forest@narfu.ru
http://lesnoizhurnal.ru/en/

RussianEnglish



Archive

The Regional and Age-Related Changes of Hardwood Lignin-Carbohydrate Matrix Chemical Composition in Terms of Aspen (Populus Tremula)

Версия для печати
Creative Commons License
These works are licensed under a Creative Commons Attribution 4.0 International License.

M.A. Pustynnaya, M.A. Gusakova, K.G. Bogolitsyn

Complete text of the article:

Download article (pdf, 0.5MB )

UDС

630*811; 630*812/813; 547.992.3

DOI:

10.17238/issn0536-1036.2015.1.133

Abstract

The demand for semi-finished fiber for paper and paperboard manufacturing is increased significantly as a result of their consumption. Improvement of wood raw material consumption structure leads to increase of fast-growing hardwood allocated for processing. Data on the structure, composition and properties of wood, wood components transformation regularities at the molecular and supramolecular levels in the chemical and physical impacts are needed for the industrial processing control and product quality. Several factors, such as complex of climatic conditions, age of a tree and felling time, influence on the content and distribution of the main components of wood, even within the same species. In recent decades many scientists pay their attention to the aspen wood in genetic and biochemical studies, and consider the aspen wood as a potential raw material for the pulp and paper industry in the development of chemi-thermomechanical pulp and some other fibrous materials. The purpose of this paper is to show the influence of abiotic factors and lifetime on the chemical composition of the fast-growing hardwood in terms of an aspen. To achieve this purpose it is necessary to: - investigate the chemical composition of mixed-age aspen wood, selected in different climatic zones; - evaluate the influence of abiotic factors on the content of the main components of wood; - assess the impact of the tree life time to change the content of basic chemical components of wood. The stick of aspen age from 10 to 45 years was felled for the study. Aspen wood was collected in the natural stands in the summer on the territory of the northern and central areas of the taiga. The paper presents the results of a study of volume components of the all-aged wood of aspen (Populus tremula). For a reliable assessment of the total value of the lignin content at aspen wood it is necessary to consider the content of acid-soluble fraction, which increases the value of lignin in wood. Mild climate conditions of the middle taiga allow the carbohydrate components biosynthesis to dominate, which is reflected in the higher content of cellulose compared with the samples from the northern taiga. These data indicate the dependencies of the content of cellulose and lignin on the abiotic factors, and the dependencies of the age of wood and the lignin content. As for the changes in the content of alcohol-soluble extractives with aging we can note the minor variations and the stable pattern in their content.

Authors

M.A. Pustynnaya1, Postgraduate M.A. Gusakova1, Candidate of Engineering K.G. Bogolitsyn1,2, Doctor of Chemistry, Professor

Affiliation

1Institute of Ecological Problems of the North, Ural Branch of the Russian Academy of Sciences, Naberezhnaya Severnoy Dviny, 23, Arkhangelsk, 163000; Russia; e-mail: lobanova2806@gmail.com; ph.: (8182) 28-55-40  2Northen (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russia

Keywords

aspen, abiotic factors, cellulose, acid-soluble lignin, Klason lignin, extractives, hydrolyzable polysaccharides.

References

1. Atlas Arhangel'skoj oblasti [Atlas of the Arkhangelsk Region]. Ed. by D.F. Fedorov. Мoscow, 1976. 72 p. 2. Akim E.L., Molotkov L.K. Proekt «Listvennica». Biorefajning osiny [The Project "Larch". Biorefayning of Aspen]. Tselluloza. Bumaga. Karton, 2011, no. 8, pp. 26 - 31. 3. Besschetnov V.P., Besschetnova N.N. Obrazovanie i lignifikacija ksilemy pljusovyh derev'ev sosny obyknovennoj [Formation and Lignification of the Xylem of Scots Pine Seed-Production Trees]. Lesnoy zhurnal, 2013, no. 2. 4. Bogolitsyn K.G., Reznikov V.M. Himija sul'fitnyh metodov delignifikacii [Chemistry of Sulfite Methods of Delignification]. Мoscow, 1994. 420 p. 5. Brauns F.E., Brauns D.A. Himija lignina [Chemistry of Lignin]. Мoscow, 1964. 864 p. 6. Buchelnikova Ya.V. Osobennosti ispol'zovanija osinovoj drevesiny pri proizvodstve himiko-termomehanicheskoj massy: dis. ... kand. tech. nauk [Usage Features of Aspen Wood in the Manufacture of Chemithermomechanical Pulp: Cand. Eng. Sci. Diss.]. Moscow, 2011. 146 p. 7. Geles I.S. Drevesnoe syr'e - strategicheskaja osnova i rezerv civilizacii [Wood Raw Materials - a Strategic Framework and Provision of Civilization]. Petrozavodsk, 2007. 500 p. 8. Gorshkova T.A. Biogenez rastitel'nyh volokon [Biogenesis of Plant Fibers]. Мoscow, 2009. 260 p. 9. Grushnikov O.P., Yolkin V.V. Dostizhenija i problemy himii lignina [Achievements and Challenges of Lignin Chemistry]. Мoscow, 1973. 296 p. 10. Ivanter E.V., Korosov A.V. Jelementarnaja biometrija [Elementary Biometrics]. Petrozavodsk, 2010. 104 p. 11. Yeliseev S.G. Tehnicheskie i jekspluatacionnye svojstva drevesiny morfologicheskih form osiny: dis. ... kand. tech. nauk [Technical and Operational Properties of Wood of Morphological Forms of Aspen: Cand. Eng. Sci. Diss.]. Krasnoyarsk, 2010. 119 p. 12. Zheldak V. Voprosy sovershenstvovanija normativno-metodicheskogo reglamentirovanija lesovodstvennyh meroprijatij, sohranenija i usilenija jekologicheskoj, prirodoohrannoj roli lesov [Questions to Improve the Regulatory and Methodical Regulation of Silvicultural Events, Conservation and Consolidation of Ecological, Environmental Role of Forests]. Ustoichivoye lesopolzovanie, 2013, no. 1 (34), pp. 45 - 52. 13. Zarubin M.Ya. Reakcija lignina pri sol'volize rastvorami kislot i osnovanij: dis. … dokt. him. nauk [Reaction of Lignin at Solvolysis by Acids and Bases Solutions: Dr. Chem. Sci. Diss.]. Leningrad, 1976. 429 p. 14. Zubov I.N., Khviyuzov S.S., Lobanova M.A., Gusakova M.A., Bogolitsyn K.G. Vlijanie abioticheskih faktorov na formirovanie lignouglevodnoj matricy drevesiny mozhzhevel'nika [Influence of Abiotic Factors on the Formation of Lignin-Carbohydrate Matrix of Juniper Wood]. Lesnoy zhurnal, 2012, no. 1, pp. 113 – 120. 15. Lebedev K.K. Issledovanija po himii lignina [Studies on the Chemistry of Lignin]. Moscow, 1965. 292 p. 16. Mikhailov L.E. Osinniki: monograf. [Aspen: Monograph]. Мoscow, 1972. 119 p. 17. Nevolin V.F., Poluboyarinov O.I., Zarudnaya G.I. Tehnologija celljulozno-bumazhnogo proizvodstva [Technology of Pulp and Paper Production]. Saint Petersburg, 2002, vol. 1. 432 p. 18. Nikitin N.I. Himija drevesiny i celljulozy [Chemistry of Wood and Cellulose]. Мoscow – Leningrad, 1962. 711 p. 19. Obolenskaya A.V., Yelnitskaya Z.P., Leonovich A.L. Laboratornye raboty po himii drevesiny i celljulozy [Laboratory Works on the Chemistry of Wood and Cellulose]. Мoscow, 1991. 320 p. 20. Sarkanen K.V. Ligniny (struktura, svojstva, reakcii) [Lignans (Structure, Properties, Reaction)]. Мoscow, 1975. 632 p. 21. Fengel D., Vegener G. Drevesina (himija, ul'trastruktura, reakcii) [Wood (Chemistry, Ultrastructure, Reactions)]. Мoscow, 1988. 512 p. 22. Chuiko V.A. Tendencii razvitija rossijskoj CBP [Trends in the Development of the Russian Pulp and Paper Industry]. Tselluloza. Bumaga. Karton, 2012, no. 1, pp. 3 -7. 23. Browning B.L., Bublitz I.O. The Isolation of Holocellulose from Wood. Tappi, 1953, no. 36, pp. 452-458. 24. McDonald I. R. C., Campbell W. G. Acid-Soluble Lignin. Nature, 1952, no. 169, p. 33. 25. Stumpf, W., Freudenberg, K. L?sliches Lignin aus Fichten- und Buchenholz. Angewandte Chemie, 1950, vol. 62, no. 22, p. 537.

The Regional and Age-Related Changes of Hardwood Lignin-Carbohydrate Matrix Chemical Composition in Terms of Aspen (Populus Tremula)

 

Make a Submission


ADP_cert_2024.png

Lesnoy Zhurnal (Russian Forestry Journal) was awarded the "Seal of Recognition for Active Data Provider of the Year 2024"

INDEXED IN: 

scopus.jpg

DOAJ_logo-colour.png

logotype.png

Логотип.png