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Surface Treatment of Cardboard with Plant and Bacterial Derived Nanocellulose Suspensions. P. 162–172

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Е.А. Toptunov, Yu.V. Sevastyanova, K.S. Vashukova

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UDС

676.168

DOI:

10.37482/0536-1036-2023-3-162-172

Abstract

This study investigates powdered cellulose materials, particularly nanocellulose derived from plant and bacterial sources. The nanocellulose was generated by hydrolyzing bleached sulphate softwood and hardwood pulp samples with strong acids. The original materials are present in the product lines of leading Russian pulp and paper companies. The bacterial cellulose was produced under laboratory conditions from Medusomyces gisevii. The dimensional parameters of the nanocellulose samples were evaluated using electron microscopy, and the degree of polymerization was measured by determining the viscosity of the cellulose solutions in cadoxene. The bleached softwood pulp had a nanocellulose particle length of 80–200 nm, a particle diameter of 80–100 nm, and a degree of polymerization of 60. The bleached hardwood pulp had a particle length of 80–150 nm, a particle diameter of 70–100 nm, and a degree of polymerization of 50. The bacterial nanocellulose had a particle length of 120–250 nm, a particle diameter of 70–120 nm, and a degree of polymerization of 110. Suspensions of various concentrations (from 1 to 10 %) were prepared from nanocellulose samples, which were subsequently used as reinforcing additives in cardboard samples. The additive was applied to the surface in one or two layers. Additives of nanocellulose preparations reduced the breaking length (from 9.6 to 40.4 %) along with an increase in cardboard density (from 6.3 to 23.8 %), tensile rigidity (from 14.0 to 25.0 %) and bursting strength (up to 31.9 %). The best results were obtained by applying a nanocellulose suspension of bleached softwood pulp to the board surface in two layers: a 9.6 % decrease in breaking length was observed with an increase in density of 23.8 %, tensile rigidity of 25.0 %, and bursting resistance of 31.9 % relative to the control sample. Therefore, the study showed the possibility of using nanocellulose suspensions derived from plants and bacterial sources by acid hydrolysis for the surface treatment of cardboard.

Authors

Еvgeniy А. Toptunov*, Engineer; ResearcherID: ABE-4069-2020, ORCID: https://orcid.org/0000-0001-8441-788X
Yuliya V. Sevastyanova, Candidate of Engineering, Assoc. Prof.; ResearcherID: ABE-4746-2020, ORCID: https://orcid.org/0000-0002-1806-9052
Ksenia S. Vashukova, Candidate of Engineering, Assoc. Prof.; ResearcherID: G-1760-2019, ORCID: https://orcid.org/0000-0002-7916-2410

Affiliation

Northern (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russian Federation; zhenyatope@gmail.com*, y-sevastyanova@yandex.ru, k.bolotova@narfu.ru

Keywords

powdered cellulose materials, nanocrystalline cellulose, nanofibrillar cellulose, bacterial nanocellulose, freeness value, degree of polymerization, structural and morphological characteristics

For citation

Toptunov Е.А., Sevastyanova Yu.V., Vashukova K.S. Surface Treatment of Cardboard with Plant and Bacterial Derived Nanocellulose Suspensions. Lesnoy Zhurnal = Russian Forestry Journal, 2023, no. 3, pp. 162–172. (In Russ.). https://doi.org/10.37482/0536-1036-2023-3-162-172

References

  1. Voskoboynikov I.V., Kondratyuk V.A., Nikolskiy S.N., Konstantinova S.A., Korotkov A.N. Application of Nanocellulose Hydrogels in the Formation of Paper, and Cardboard from Different Types of Fibrous Raw Materials. Lesnoj vestnik = Forestry Bulletin, 2012, no. 8, pp. 110–116. (In Russ.).

  2. Gismatulina Yu.A., Budaeva V.V., Sitnikova A.E., Bychin N.V., Gladysheva E.K., Shavyrkina N.A., Mironova G.F., Sevastyanova Yu.V. Bacterial Nanocellulose and Softwood Pulp for Composite Paper. Izvestiya vuzov. Prikladnaya ximiya i biotexnologiya. = Proceedings of Universities Applied Chemistry and Biotechnology, 2021, vol. 11, no. 3, pp. 460–471. (In Russ.). https://doi.org/10.21285/2227-2925-2021-11-3-460-471

  3. Zarubina A.N., Ivankin A.N. Kuleznev A.S., Kochetkov V.A. Сellulose and Nanocellulose. Review. Lesnoj vestnik = Forestry Bulletin, 2019, vol. 23, no. 5, pp. 116–125. (In Russ.). https://doi.org/10.18698/2542-1468-2019-5-116-125

  4. Ioelovich M.Ya. Optimization of Process for Production of Nanocrystalline Cellulose and Its Composites. Khimiya Rastitel’nogo Syr’ya = Chemistry of Plant Raw Material, 2021, no. 1, pp. 55–61 (In Russ.). https://doi.org/10.14258/jcprm.2021018667

  5. Kuznetsova T.G., Selivanova E.B., Bogdanova A.V., Ivankin A.N. Nanoidentification Nanocomposite in Raw Materials and Food Products. Ekologicheskiye sistemy i pribory = Ecological Systems and Devices, 2012, no. 2, pp. 18–22. (In Russ.).

  6. Proshina O.P., Oliferenko G.L., Evdokimov Yu.M., Ivankin A.N. Nano-Cellulose and Reception of a Paper on Its Basis. Nanotechnologies and Nanomaterials in the Forest Complex: Proceedings of the International Conference, Moscow, 15–17 November 2011. Moscow, BMSTU Publ., 2011, pp. 24–28. (In Russ.).

  7. Semkina L.I., Sarana N.V., Lepeshkina E.V., Tovstoshkurov E.M., Goraychev N.L., Tyurin E.T., Zuikov A.A., Konstantinova S.A., Novikov A.A. Nanofibrillated Cellulose in Corrugating Paper Composition. Lesnoj vestnik = Forestry Bulletin, 2020, vol. 24, no. 2, pp. 119–126. (In Russ.). https://doi.org/10.18698/2542-1468-2020-2-119-126

  8. Toptunov E.A., Sevastyanova Yu.V. Powdered Cellulosic Materials: Overview, Classification, Characteristics and Fields of Application. Khimiya Rastitel’nogo Syr’ya = Chemistry of Plant Raw Material, 2021, no. 4, pp. 31–45. (In Russ.). https://doi.org/10.14258/jcprm.2021049186

  9. Tyurin E.T., Zuikov A.A., Bondarev A.I., Gulyanz L.P., Fadeeva L.A., Konstantinova S.A., Novikov A.A., Anikuchin B.M., Vinokurov V.A. Testing of Experimental Samples of Nanofibrillar Cellulose in the Production of Lightweight Coated Paper. Lesnoj vestnik = Forestry Bulletin, 2021, vol. 25, no. 2, pp. 90–98. (In Russ.). https://doi.org/10.18698/2542-1468-2021-2-90-98

  10. Abitbol T., Amit R., Yifeng C., Yuval N., Eldho A., Tal B.-S., Shaul L., Oded S. Nanocellulose, a Tiny Fiber with Huge Applications. Current Opinion in Biotechnology, 2016, vol. 39, pp. 76–88. https://doi.org/10.1016/j.copbio.2016.01.002

  11. Bras J., Hassan M.L., Bruzesse C., Hassan E.A., El-Wakil N.A., Dufresne A. Mechanical, Barrier, and Biodegradability Properties of Bagasse Cellulose Whiskers Reinforced Natural Rubber Nanocomposites. Industrial Crops and Products, 2010, vol. 32, no. 3, pp. 627–633. https://doi.org/10.1016/j.indcrop.2010.07.018

  12. Camarero Espinosa S., Kuhnt T., Foster E.J., Weder C. Isolation of Thermally Stable Cellulose Nanocrystals by Phosphoric Acid Hydrolysis. Biomacromolecules, 2013, vol. 14, no. 4, pp. 1223–1230. https://doi.org/10.1021/bm400219u

  13. Grinshpan D.D., Gonchar A.N., Savitskaya T.A., Tsygankova N.G., Makarevich S.E. Rheological Properties of Cellulose-Chitosan-Phosphoric Acid Systems in Different Phase States. Polymer Science, Series A, 2014, vol. 56, no. 2, pp. 137–145. https://doi.org/10.1134/S0965545X14020059

  14. Hayase G., Kanamori K., Hasegawa G., Maeno A., Kaji H., Nakanishi K. A Superamphiphobic Macroporous Silicone Monolith with Marshmallow-Like Flexibility. Angewandte Chemie, 2013, vol. 52, no. 41, pp. 10788–10791. https://doi.org/10.1002/anie.201304169

  15. Jorfi M., Foster J.E. Recent Advances in Nanocellulose for Biomedical Applications. Journal of Applied Polymer Science, 2015, vol. 132, no. 14, рр. 1–19. https://doi.org/10.1002/app.41719

  16. Lin N., Dufresne A. Nanocellulose in Biomedicine: Current Status and Future Prospect. European Polymer Journal, 2014, vol. 59, pp. 302–325. https://doi.org/10.1016/j.eurpolymj.2014.07.025

  17. Liu K., Tian Y., Jiang L. Bio-Inspired Superoleophobic and Smart Materials: Design, Fabrication, and Application. Progress in Materials Science, 2013, vol. 58, no. 4, pp. 503–564. https://doi.org/10.1016/j.pmatsci.2012.11.001

  18. Moon R.J., MartiniA., Nairn J., Simonsen J., Youngblood J. Cellulose Nanomaterials Review: Structure, Properties and Nanocomposites. Chemical Society Reviews, 2011, vol. 40, no. 7, pp. 3941–3994. https://doi.org/10.1039/c0cs00108b

  19. Revol J.F., Bradford H., Giasson J., Marchessault R.H., Gray D.G. Helicoidal Self-Ordering of Cellulose Microfibrils in Aqueous Suspension. International Journal of Biological Macromolecules, 1992, vol. 14, no. 3, pp. 170–172. https://doi.org/10.1016/S0141-8130(05)80008-X

  20. Robles E., Urruzola I., Labidi J., Serrano L. Surface-Modified Nano-Cellulose as Reinforcement in Poly (Lactic Acid) to Conform New Composites. Industrial Crops and Products, 2015, vol. 71, pp. 44–53. https://doi.org/10.1016/j.indcrop.2015.03.075

  21. Si Y., Guo Z. Superhydrophobic Nanocoatings: From Materials to Fabrications and to Applications. Nanoscale, 2015, vol. 7, no. 14, pp. 5922–5946. https://doi.org/10.1039/C4NR07554D

  22. Siqueira G., Bras J., Dufresne A. Cellulosic Bionanocomposites: A Review of Preparation, Properties and Applications. Polymers, 2010, vol. 2, no. 4, pp. 728–765. https://doi.org/10.3390/polym2040728

  23. Wei H., Rodriguez K., Renneckar S., Vikesland P.J. Environmental Science and Engineering Applications of Nanocellulose-Based Nanocomposites. Environmental Science. Nano, 2014, vol. 1, no. 4, pp. 302–316. https://doi.org/10.1039/C4EN00059E



 

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