![]() Address: 17 Naberezhnaya Severnoy Dviny, Arkhangelsk 163002 Russian Federation. Northern (Arctic) Federal University named after M.V.Lomonosov. Office 1425
Phone / Fax: (818-2) 21-61-18 Archive |
![]() These works are licensed under a Creative Commons Attribution 4.0 International License. V.A. Plakhin, Yu.G. Khabarov, V.A. Veshnyakov Complete text of the article:Download article (pdf, 0.7MB )UDС676.084.2+546.57AbstractColloidal silver solutions can be used as catalysts for carrying out various chemical transformations of organic substances and solving the problems of disposal of toxic compounds, as well as antibacterial agents for combating pathogenic microflora, in the manufacture of lubricants and light-absorbing materials, coatings, sensors, conductive pastes, and high-performance electrode materials. The research purpose is to study the synthesis of colloidal silver using a solution of technical lignosulfonates (LST) as a stabilizer. Colloidal silver was synthesized as a result of the reduction-oxidation (redox) reaction of Ag(I) cations with glucose at 100 °C in the presence of lignosulfonates. The reaction was carried out in an alkaline medium, which is provided by the addition of ammonia water. Electronic spectroscopy was used to control the synthesis of colloidal silver. After the reaction, the solution turned dark brown and an intense absorption band with a maximum at 400 nm appeared on the electron spectra. The effects of reagent consumption and synthesis duration were studied. It was found that the optimal reagent consumption in the colloidal silver synthesis is as follows: 2.5–5 g glucose / g Ag, 0.3–1 g LST / g Ag, and 3–5 g NH3 / g Ag. The synthesis duration is 2–5 min. The resulting colloidal silver solution is stable for several months. Partial stratification without precipitation is observed during the solution storage. It is shown experimentally that the stratification is followed by a redistribution of colloidal silver particles. Electron spectroscopy confirmed the absence of colloidal silver particles in the upper layer. The reaction kinetics has been studied in experiments carried out under thermostatically controlled conditions at temperatures from 50 to 100 °C. The kinetic dependence is described by a first-order equation at the initial stage of the reaction, the duration of which depends on the temperature. The duration of the active part of the kinetic curves is 15–90 % of the total reaction time. The logarithm of the rate constant on the active section was proved to depend linearly on the reverse thermodynamic temperature (pair correlation coefficient is 0.9887). The activation energy was 47 kJ/mol.AuthorsVadim A. Plakhin, Postgraduate Student; ResearcherID: AAH-6544-2020, ORCID: https://orcid.org/0000-0001-9143-1663Yuriy G. Khabarov, Doctor of Chemistry, Prof.; ResearcherID: P-1802-2015, ORCID: https://orcid.org/0000-0001-8392-0985 Viacheslav A. Veshnyakov, Candidate of Chemistry; ResearcherID: E-3882-2017, ORCID: https://orcid.org/0000-0002-8278-5053 AffiliationNorthern (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russian Federation; е-mail: v.plahin@narfu.ru, khabarov.yu@mail.ru, viacheslav.veshnyakov@mail.ruKeywordsnanosilver, lignosulfonates, reduction reaction, colloidal solutions, glucoseFor citationPlakhin V.A., Khabarov Yu.G., Veshnyakov V.A. Synthesis of Colloidal Silver Using Lignosulfonates. Lesnoy Zhurnal [Russian Forestry Journal], 2021, no. 6, pp. 184–195. DOI: 10.37482/0536-1036-2021-6-184-195References1. Плахин В.А., Вешняков В.А., Хабаров Ю.Г., Чухчин Д.Г. Свойства продуктов взаимодействия катионов железа(II) с аммиакатом серебра в присутствии лигносульфонатов // Физикохимия растительных полимеров: материалы VIII междунар. конф. Архангельск: САФУ. 2019. С. 114–117. Plakhin V.A., Veshnyakov V.A., Khabarov Yu.G., Chukhchin D.G. Properties of the Products of Interaction of Iron(II) Cations with Silver Ammonia in the Presence of Lignosulfonates. Proceedings of the VIII International Conference “Physicochemistry of Plant Polymers”. Arkhangelsk, NArFU, 2019, pp. 114–117. 2. Benet W.E., Lewis G.S., Yang L.Z., Hughes D.E.P. The Mechanism of the Reaction of the Tollens Reagent. Journal of Chemical Research, 2011, vol. 35, no. 12, pp. 675–677. DOI: https://doi.org/10.3184/174751911X13206824040536 3. Chen L., Xiang Y. Preparation Method for Lignosulfonate Nano-Silver Colloid. Patent CN no. CN 102489716 B, 2012. 4. Dumitriu R.P., Niţă L.E., Sacarescu L., Vasilescu D.S. Preparation of Silver Nanoparticle Dispersion by a Green Synthesis Method. University Politehnica of Bucharest Scientific Bulletin Series B: Chemistry and Materials Science, 2015, vol. 77, iss. 2, pp. 81–90. 5. Jiang M., Liu J., Zhu C. A Kind of Preparation Method of High-Purity Nano Silver Paste. Patent CN no. CN 108620604 A, 2018. 6. Kheybari S., Samadi N., Hosseini S.V., Fazeli A., Fazeli M.R. Synthesis and Antimicrobial Effects of Silver Nanoparticles Produced by Chemical Reduction Method. DARU Journal of Pharmaceutical Sciences, 2010, vol. 18, iss. 3, pp. 168–172. 7. Konował E., Sybis M., Modrzejewska-Sikorska A., Milczarek G. Synthesis of Dextrin-Stabilized Colloidal Silver Nanoparticles and Their Application as Modifiers of Cement Mortar. International Journal of Biological Macromolecules, 2017, vol. 104, pp. 165–172. DOI: https://doi.org/10.1016/j.ijbiomac.2017.06.011 8. Li M., Jiang X., Wang D., Xu Z., Yang M. In situ Reduction of Silver Nanoparticles in the Lignin Based Hydrogel for Enhanced Antibacterial Application. Colloids and Surfaces B: Biointerfaces, 2019, vol. 177, pp. 370–376. DOI: https://doi.org/10.1016/j.colsurfb.2019.02.029 9. Milczarek G., Motylenko M., Modrzejewska-Sikorska A., Klapiszewski Ł., Wysokowski M., Bazhenov V.V., Piasecki A., Konował E., Ehrlich H., Jesionowski T. Deposition of Silver Nanoparticles on Organically-Modified Silica in the Presence of Lignosulfonate. RSC Advances, 2014, vol. 4, no. 94, pp. 52476–52484. DOI: https://doi.org/10.1039/C4RA08418G 10. Milczarek G., Rebis T., Fabianska J. One-Step Synthesis of Lignosulfonate-Stabilized Silver Nanoparticles. Colloids and Surfaces B: Biointerfaces, 2013, vol. 105, pp. 335–341. DOI: https://doi.org/10.1016/j.colsurfb.2013.01.010 11. Mimini V., Kabrelian V., Fackler K., Hettegger H., Potthast A., Rosenau T. Lignin-Based Foams as Insulation Materials: A Review. Holzforschung, 2018, vol. 73, iss. 1, pp. 117–130. DOI: https://doi.org/10.1515/hf-2018-0111 12. Modrzejewska-Sikorska A., Konował E., Cichy A., Nowicki M., Jesionowski T., Milczarek G. The Effect of Silver Salts and Lignosulfonates in the Synthesis of Lignosulfonate-Stabilized Silver Nanoparticles. Journal of Molecular Liquids, 2017, vol. 240, pp. 80–86. DOI: https://doi.org/10.1016/j.molliq.2017.05.065 13. Natsuki J., Natsuki T., Hashimoto Y. A Review of Silver Nanoparticles: Synthesis Methods, Properties and Applications. International Journal of Materials Science and Applications, 2015, vol. 4, iss. 5, pp. 325–332. DOI: https://doi.org/10.11648/j.ijmsa.20150405.17 14. Raveendran P., Fu J., Wallen S.L. A Simple and “Green” Method for the Synthesis of Au, Ag, and Au-Ag Alloy Nanoparticles. Green Chemistry, 2006, vol. 8, iss. 1, pp. 34–38. DOI: https://doi.org/10.1039/B512540E 15. Shameli K., Bin Ahmad M., Jazayeri S.D., Sedaghat S., Shabanzadeh P., Jahangirian H., Mahdavi M., Abdollahi Y. Synthesis and Characterization of Polyethylene Glycol Mediated Silver Nanoparticles by the Green Method. International Journal of Molecular Sciences, 2012, vol. 13, iss. 6, pp. 6639–6650. DOI: https://doi.org/10.3390/ijms13066639 16. Sybis M., Konowal E., Modrzejewska-Sikorska A. Bakteriobójcza aktywność koloidów srebra stabilizowanych hydrolizatami skrobiowymi oraz ich wpływ na wytrzymałość zapraw cementowych. Acta Scientiarum Polonorum Architectura, 2017, vol. 16, no. 4, pp. 37–46. DOI: https://doi.org/10.22630/ASPA.2017.16.4.04 17. Wang Y., Li Z., Yang D., Qiu X., Xie Y., Zhang X. Microwave-Mediated Fabrication of Silver Nanoparticles Incorporated Lignin-Based Composites with Enhanced Antibacterial Activity via Electrostatic Capture Effect. Journal of Colloid and Interface Science, 2020, vol. 583, pp. 80–88. DOI: https://doi.org/10.1016/j.jcis.2020.09.027 18. Xiang Y., Xu W., Zhan Y., Xia X., Xiong Y., Xiong Y., Chen L. Preparation of Modified Sodium Lignosulfonate Hydrogel–Silver Nanocomposites. Polymer Composites, 2013, vol. 34, iss. 6, pp. 860–866. DOI: https://doi.org/10.1002/pc.22490 19. Xue Y., Qiu X., Liu Z., Li Y. Facile and Efficient Synthesis of Silver Nanoparticles Based on Biorefinery Wood Lignin and Its Application as the Optical Sensor. ACS Sustainable Chemistry & Engineering, 2018, vol. 6, iss. 6, pp. 7695–7703. DOI: https://doi.org/10.1021/acssuschemeng.8b00578 Synthesis of Colloidal Silver Using Lignosulfonates |
Make a Submission
Lesnoy Zhurnal (Russian Forestry Journal) was awarded the "Seal of Recognition for Active Data Provider of the Year 2024" INDEXED IN:
|
![]() |
|
![]() |
![]() |
![]() |
|
![]() |
|
![]() |
|
![]() |
|
![]() |
![]() |
![]() |
|
![]() |
![]() |
![]() |
|
![]() |
![]() |
![]() |
|
![]() |
![]() |
![]() |
|
![]() |
|
![]() |
![]() |
![]() |
![](/img/transparent.gif)