Address: 17 Naberezhnaya Severnoy Dviny, Arkhangelsk 163002 Russian Federation. Northern (Arctic) Federal University named after M.V.Lomonosov. Office 1425

Phone / Fax: (818-2) 21-61-18
E-mail: forest@narfu.ru
http://lesnoizhurnal.ru/en/

RussianEnglish



Archive

Influence of Cardboard Pretreatment on the Determination of Starch Content by the Enzymatic Method

Версия для печати
Creative Commons License
These works are licensed under a Creative Commons Attribution 4.0 International License.

I.A. Khadyko, E.V. Novozhilov, D.G. Chukhchin

Complete text of the article:

Download article (pdf, 1.6MB )

UDС

543.635.252

Abstract

We determined the amount of starch by the enzymatic method in different samples of corrugated cardboard, including the sample produced of primary semi-finished products and corrugated cardboard made of 100 % waste paper. For starch enzymatic degradation, it is necessary to extract it from the corrugated board structure, since the processes of compression and keratinization of pulp fibers reduce the availability of starch for extraction. Enzymatic treatment requires the use of a complex amylolytic preparation for complete hydrolysis of starch to glucose. We were able to determine, respectively, 70 and 84 % of starch obtained from primary semi-finished products by mechanical methods, such as defibrillation in water and degradation in a liquid nitrogen medium, and added at the production stage of corrugated cardboard. It was shown that extraction with alkaline agents was necessary for more complete extraction of starch from corrugated cardboard. The influence of alkaline treatment on the characteristics of fibers of waste paper fractions obtained at the Sukhonsky Cardboard and Paper Mill has been analyzed. The fibers swell in alkali, resulting in an increase in fiber width and its shortening, as well as a decrease in crystallinity, which can be a positive opportunity for more complete starch extraction. Fiber swelling and crystallinity reduction are more intensive for the short fiber fraction compared to the long fiber fraction. When determining starch in corrugated cardboard using the standard method SCAN-P 91:09 SСAN-W 13:09 it was not possible to detect all the starch added at the production stage of corrugated cardboard from primary semi-finished products. Also the processing conditions of this methodology lead to degradation of the partially hydrolyzed starch. The most complete extraction of starch from corrugated cardboard was achieved by two stages of alkaline extraction under the following conditions: 5 % NaOH, temperature of 20 °C, the duration of each extraction – 2 h. Under these processing conditions it was possible to determine all the starch (22.8 kg/t) in the corrugated cardboard produced of primary semi-finished products with known consumption of starch; the starch content in the corrugated cardboard produced of 100 % waste paper was 48.2 kg/t.

Authors

Igor A. Khadyko, Senior Lecturer; ResearcherID: N-1537-2017, ORCID: https://orcid.org/0000-0001-7128-1688
Evgeny V. Novozhilov, Doctor of Engineering, Prof.; ResearcherID: O-9738-2015, ORCID: https://orcid.org/0000-0003-3642-3307
Dmitry G. Chukhchin, Candidate of Engineering, Prof.; ResearcherID: O-9487-2015, ORCID: https://orcid.org/0000-0003-3250-8469

Affiliation

Northern (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russian Federation; e-mail: i.hadiko@narfu.ru

Keywords

corrugated cardboard, starch, starch determination, amylolytic enzymes, defibrillation, waste paper

Funding

The reported study was funded by the Russian Foundation for Basic Research within the framework of the research project No. 20-04-00457 “Pits in the Anatomical Elements of the Xylem of Higher Plants: Formation, Morphology and Functions”.

For citation

Khadyko I.A., Novozhilov E.V., Chukhchin D.G. Influence of Cardboard Pretreatment on the Determination of Starch Content by the Enzymatic Method. Lesnoy Zhurnal [Russian Forestry Journal], 2021, no. 5, pp. 150–162. DOI: 10.37482/0536-1036-2021-5-150-162

References

Dul’kin D.A., Spiridonov V.A., Komarov V.I. Current State and Prospects of the Use of Recycled Fiber from Waste Paper in the Global and Domestic Paper Industry. Arkhangelsk, ASTU Publ., 2007. 1118 p.

D’yakova E.V., Dul’kin D.A., Komarov V.I. Waste Paper Recycling. Arkhangelsk, ASTU Publ., 2009. 172 p.

Zalevskaya Yu.M., Belik E.S., Burmistrova M.V. Wastewater Treatment Pulp and Paper Industry. Proceedings of the XIII All-Russian Scientific and Practical Conference of Students, Postgraduate Students and Young Scientists “Ecology, Scientific and Technological Progress. Urban Studies”. Perm, PNRPU, 2015, vol. 1, pp. 137–144.

Lapin V.V., Smolyakov A.I., Kudrina N.D. Impurities in Paper Pulp Made of 100 % Waste Paper: Influence on the Degree of Grinding and Strength of Paper and Cardboard. Tsellyuloza. Bumaga. Karton, 2001, no. 7-8, pp. 32–34.

Lapin V.V., Smolyakov A.I., Kudrina N.D. The Problem of Strength Properties of Corrugated Paper and Cardboard for Liners of 70–100 % Waste Paper: The Role of Grinding. Tsellyuloza. Bumaga. Karton, 2002, no. 9-10, pp. 32–34.

Mihailova O.S., Kryakounova E.V., Kanarskii A.V., Kazakov Y.V., Dulkin D.A. Effect of Enzymatic Treatment of Potato Starch on the Physical and Mechanical Properties of Paper. Vestnik tekhnologicheskogo universiteta [Bulletin of the Technological University], 2015, vol. 18, no. 4, pp. 203–207.

Novozhilov E.V. Application of Enzyme Technologies in Pulp and Paper Industry. Arkhangelsk, NArFU Publ., 2013. 364 p.

Flyate D.M. Properties of Paper. Saint Petersburg, Lan’ Publ., 2012. 384 p.

Khadyko I.A., Kazakov Y.V., Novozhilov E.V., Kanarskii A.V. The Use of Enzymes for the Assessment of Biodegradation of Materials by the Express Method. Vestnik Kazanskogo tekhnologicheskogo universiteta [Bulletin of the Technological University], 2014, vol. 17, no. 13, pp. 277–280.

Khadyko I.A., Novozhilov E.V., Prigodich Y.A., Kanarskiy A.V. Enzymatic Method for Determination of Starch in Paper and Cardboard. Vestnik tekhnologicheskogo universiteta [Bulletin of the Technological University], 2017, vol. 20, no. 7, pp. 156–159.

Alexandersson T. Water Reuse in Paper Mills. Measurements and Control Problems in Biological Treatment. Licentiate Thesis. Lund, Sweden, Lund University, 2003. 126 p.

Baсеrra V., Оdеrmatt J. Direct Determination of Cationic Starches in Paper Samples Using Analytical Pyrolysis. Journal of Analytical and Applied Pyrolysis, 2014, vol. 105, pp. 348–354. DOI: https://doi.org/10.1016/j.jaap.2013.11.024

Bogolitsyn K.G., Zubov I.N., Gusakova M.A., Chukhchin D.G., Krasikova A.A. Juniper Wood Structure under the Microscope. Planta, 2015, vol. 241, iss. 5, pp. 1231–1239. DOI: https://doi.org/10.1007/s00425-015-2252-1

Hernadi A., Lele I. Improving the Recycled Fibre Performance by Means of α-Amylase Treatment. Papiripar, 2004, vol. 48, no. 3, pp. 97–106.

Hubbe M.A., Venditti R.A., Rojas O.J. What Happens to Cellulosic Fibers during Papermaking and Recycling? A Review. BioResources, 2007, vol. 2(4), pp. 739–788. DOI: https://doi.org/10.15376/biores.2.4.739-788

SCAN-P 91:09 SCAN-W 13:09. Paper, Board and Process Waters – Starch Content. Scandinavian Pulp, Paper and Board Testing Committee, 2008. 10 p.

TAPPI/ANSI T 419 Om-18. Starch in Paper. ANSI, 2011. 6 p.

Topgaard D., Söderman O. Changes of Cellulose Fiber Wall Structure during Drying Investigated Using NMR Self-Diffusion and Relaxation Experiments. Cellulose, 2002, vol. 9, iss. 2, pp. 139–147. DOI: https://doi.org/10.1023/A:1020158524621

Wistara N., Young R.A. Properties and Treatments of Pulps from Recycled Paper. Part I. Physical and Chemical Properties of Pulps. Cellulose, 1999, vol. 6, iss. 4, pp. 291–324. DOI: https://doi.org/10.1023/A:1009221125962


Influence of Cardboard Pretreatment on the Determination of Starch Content by the Enzymatic Method

 

Make a Submission


ADP_cert_2024.png

Lesnoy Zhurnal (Russian Forestry Journal) was awarded the "Seal of Recognition for Active Data Provider of the Year 2024"

INDEXED IN: 

scopus.jpg

DOAJ_logo-colour.png

logotype.png

Логотип.png