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Steam Charcoal Activation from Bamboo

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Chu Cong Nghi, A. А. Spitsyn, K. А. Romanenko, D. A. Ponomarev

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UDС

662.71+630*867.5

DOI:

10.17238/issn0536-1036.2018.4.140

Abstract

The paper studies the pyrolysis of bamboo stems (Bambos bambusa) to preserve the original structure in the resulting lump charcoal. Bamboo pieces are subjected to slow pyrolysis in a 4-liter stainless steel reactor equipped with an external electric heater according to the periodic scheme. Activation of lump charcoal is carried out by superheated steam at a tempera-ture of 970 °C. The authors determine the adsorption activity for iodine, specific surface area, volume and pore size distribution for the obtained monolithic nanostructured carbon material. Analysis of sorption-desorption isotherms for the resulting material and pore size distribution diagrams indicate a microporous structure of the resulting material. The volume of micropores established by four different methods, is 0.26…0.29 cm3/g and is practically independent on the method of determination. Micropores make the main contribution to the porous structure of charcoal; their volume comprises the major part (85 %) of the total volume.

Authors

Chu Cong Nghi1, Postgraduate Student
A. А. Spitsyn1, Candidate of Engineering Sciences, Associate Professor
K. А. Romanenko2, Postgraduate Student
D. A. Ponomarev1, Doctor of Chemical Sciences, Professor

Affiliation

1Saint Petersburg State Forest Technical University under name of S.M. Kirov, Institutskiy per., 5, У, Saint Petersburg, 194021, Russian Federation; e-mail: congnghich19a@gmail.com, spitsyn.andrey@gmail.com, dponomarev1@mail.ru
2Northern (Arctic) Federal University named after M.V. Lomonosov, Naberezhnaya Severnoy Dviny, 17, Arkhangelsk, 163002, Russian Federation; e-mail: kristinaromanenko@yandex.ru

Keywords

bamboo, steam activation, active carbon, monolithic carbon, pyrolysis

For citation

Chu Cong Nghi, Spitsyn A.А., Romanenko K.А., Ponomarev D.A. Steam Charcoal Activation from Bamboo. Lesnoy zhurnal [Forestry journal], 2018, no. 4, pp. 140–149. DOI: 10.17238/issn0536-1036.2018.4.140

References

1. Giles C., Ingram B., Clunie J., Lykema J., Lane J., Parfitt G., Rendall H., Roches-ter C.H., Fleer G., Hesselink F., Hough D. Adsorption From Solution at the Solid / Liquid Interface. Ed. by G.D. Parfitt, C.H. Rochester. London, Academic Press, 1983. 416 p.
2. Obolenskaya A.V., El'nitskaya Z.P., Leonovich A.A. Laboratornye raboty po khimii drevesiny i tsellyulozy [Laboratory Work on the Chemistry of Wood and Cellulose]. Moscow, Ekologiya Publ., 1991. 320 p. (In Russ.)
3. Ademiluyi F.T., Braide O. Effectiveness of Nigerian Bamboo Activated with Different Activating Agents on the Adsorption of BTX. Journal of Applied Sciences and Envi-ronmental Management, 2012, vol. 16, no. 3. pp. 267‒273.
4. Asada T., Ohkubo T., Kawata K., Oikawa K. Ammonia Adsorption on Bamboo Charcoal with Acid Treatment. Journal of Health Science, 2006, vol. 52, no. 5, pp. 585‒589.
5. Chen D., Liu D., Zhang H., Chen Y., Li Q. Bamboo Pyrolysis Using TG-FTIR and a Lab-Scale Reactor: Analysis of Pyrolysis Behavior, Product Properties, and Carbon and Energy Yields. Fuel, 2015, vol. 148, pp. 79‒86.
6. Chen D., Zhou J., Zhang Q. Effects of Heating Rate on Slow Pyrolysis Behavior, Kinetic Parameters and Products Properties of Moso Bamboo. Bioresource Technology, 2014, vol. 169, pp. 313‒319.
7. González P.G., Pliego-Cuervo Y.B. Physicochemical and Microtextural Characterization of Activated Carbons Produced from Water Steam Activation of Three Bamboo Species. Journal of Analytical and Applied Pyrolysis, 2013, vol. 99, pp. 32‒39.
8. Gu X., Wang Y., Lai Ch., Qiu J., Li Sh., Hou Y., Martens W., Mahmood N., Zhang Sh. Microporous Bamboo Biochar for Lithium-Sulfur Batteries. Nano Research, 2015, vol. 8,no. 1, pp. 129‒139.
9. Hamzah F., Sarif M., Zulkifli F.N.Z., Ismail N.H., Manaf Sh.F.A., Idris A., Ibrahim W.A., Krishnan J. Microwave-Alkali Activation on the Morphology and Structure of Bamboo Activated Carbon. Applied Mechanics & Materials, 2014, vol. 575, pp. 154‒159.
10. Hirunpraditkoon S., Tunthong N., Ruangchai A., Nuithitikul K. Adsorption Capacities of Activated Carbons Prepared from Bamboo by KOH Activation. World Academy of Science, Engineering and Technology, 2011, vol. 78, pp. 711‒715.
11. Kantarelis E., Liu J., Yang W., Blasiak W. Sustainable Valorization of Bamboo via High-Temperature Steam Pyrolysis for Energy Production and Added Value Materials. Energy & Fuels, 2010, vol. 24, no. 11, pp. 6142–6150.
12. Ma X., Yang H., Yu L., Chen Y., Li Y. Preparation, Surface and Pore Structure of High Surface Area Activated Carbon Fibers from Bamboo by Steam Activation. Materials, 2014, vol. 7, no. 6, pp. 4431‒4441.
13. Sing K.S.W. Reporting Physisorption Data for Gas / Solid Systems with Special Reference to the Determination of the Surface Area and Porosity (Recommendations 1984). Pure and Applied Chemistry, 1985, vol. 57, no. 4, pp. 603‒619.
14. Tan Z., Qiu J., Zeng H., Liu H., Xiang J. Removal of Elemental Mercury by Bamboo Charcoal Impregnated with H2O2. Fuel, 2011, vol. 90, no. 4, pp. 1471‒1475.
15. Wang S.-Y., Tsai M.-H., Lo Sh.-F., Tsai M.-J. Effects of Manufacturing Conditions on the Adsorption Capacity of Heavy Metal Ions by Makino Bamboo Charcoal. Bioresource Technology, 2008, vol. 99, no. 15, pp. 7027‒7033.
16. Wu F.-Ch., Tseng R.-L., Juang R.-Sh. Preparation of Activated Carbons from Bamboo and Their Adsorption Abilities for Dyes and Phenol. Journal of Environmental Science & Health, Part A, 1999, vol. 34, no. 9, pp. 1753–1775.
17. Zhang Y.-J., Xing Z.-J., Duan Z.-K. Effects of Steam Activation on the Pore Structure and Surface Chemistry of Activated Carbon Derived from Bamboo Waste. Applied Surface Science, 2014, vol. 315, pp. 279‒286.
18. Zhao W., Luo L., Wang H., Fan M. Synthesis of Bamboo-Based Activated Carbons with Super-High Specific Surface Area for Hydrogen Storage. BioResources, 2017, vol. 12, no. 1, pp. 1246–1262.

Received on February 14, 2018


Steam Charcoal Activation from Bamboo

 

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