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Ю.Н. Сазанов Рубрика: Химическая переработка древесины Скачать статью (pdf, 0.5MB )УДК539. 124:539.2+543.842DOI:АннотацияПредставлен материал по синтезу и применению полимер-лигнинных композитов. Акцентировано внимание на реакциях двух типов. К первому типу относятся полимераналогичные превращения, приводящие к образованию различных сополимеров (соконденсатов), ко второму – реакции модификации взаимодействующих компонентов, в которых в основном участвуют олигомерные соединения одного из партнеров реакций, в результате чего меняется функциональность одного из компонентов или образуются редкие сшивки, приводящие к существенному изменению свойств исходных реагентов. Сведения об авторах© Ю.Н. Сазанов, д-р. хим. наук, проф. Институт высокомолекулярных соединений РАН, Большой просп., 31, С.-Петербург, Россия, 199004; e-mail: sazanov@hq.macro.ru Ключевые словалигнин, синтетические полимеры, полимераналогичные превращения, модификация, термохимия, термический анализЛитература1. Арбузов В.В. Композиционные материалы из лигнинных веществ. М.: Экология, 1991. 209 с. 2. Боголицын. К.Г. «Зеленая» химия лигнина – новые аспекты // Физ. хим. лигнина: материалы. междунар. конф. Архангельск.: АГТУ, 2007. С. 16–21. 3. Богомолов Б.Д., Гельфанд Е.Д. Непрерывная технология производства сульфатного лигнина и его применение для улучшения свойств полимерных материалов. М.: Лесн. пром-сть, 1971. 342 с. 4. Кононов Г.Н. Химия древесины и ее основных компонентов. М.: МГУЛ, 1999. 247 с. 5. Лунин В.В. Зеленая химия в России // Физ. хим. лигнина: материалы междунар. конф. Архангельск: АГТУ, 2005. С. 9–10. 6. Медведева Е.Н., Бабкин В.А. Использование лигнина для синтеза ФФС // Химия в интересах устойчивого развития. 1996. Т.4. С. 333–342. 7. Окунь М.Г., Скрытник И.В., Сухановский С.И., Чудаков М.М. Применение гидролизного лигнина в производстве пластических масс // Гидролиз. и лесохим. пром-сть. 1960. № 3. C. 14–16. 8. Пономарев Д.А. Термохимия модельных соединений лигнина и их интермедиатов в реакциях гомолитической деструкции: дис. … д-ра хим. наук. СПб., 1997. 227 с. 9. Розенберг Л.В., Берлин Ад.А., Визгерн Р.В. Привитые сополимеры на основе лигносульфоната // Гидролиз. и лесохим. пром-сть. 1972. № 5. C. 16–17. 10. Резников В.М. Реакционная способность лигнина и его превращения в процессах делигнификации древесины // Хим. древесины. 1977. № 3. C. 3–23. 11. Сазанов Ю.Н., Крутов С.М., Спирина Т.Н., Костерева Т.А., Сапрыкина Н.Н., Попова Е.Н., Андреева О.А., Новоселова А.В. Привитая сополимеризация полиакрилонитрила с гидролизным лигнином // ЖПХ. 2013. Т. 86, вып. 6. С. 992–997. 12. Сазанов Ю.Н., Куликова Е.М., Федорова Г.Н., Попова Е.Н., Литвинова Л.С., Кевер.Е.Е., Мокеев М.В., Сумерский И.В., Новоселова А.В., Грибанов А.В. Потенциальная активность гидролизного лигнина в реакциях сополимеризации // ЖПХ. 2009.
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59. Vasile C., Downey M., Wong B., Macoveanu M.M., Pascu M.C., Choi J.H., Sung C.M., Baker W. Polyolefins/Lignosulfonates/ blends II Isotactic polypropy-lene/epoxymodified lignin blends // Cellulose Chem. Technol. 1998. Vol. 32. P. 61–88. 60. Vazquez G., Gonzalez J. Freire S., Antorrena G. Effect of chemical modification of lignin on the gluebond performance of lignin-phenolic resins // Bioresour. Tech. 1997. Vol. 60. iss. 3. P. 191–198. 61. Wang M., Leithch H., Xu Ch. Synthesis of phenol formaldehyde resol resins using organosolv pine lignins // Europ. Polymer J. 2009. Vol. 45, N 12. P. 3380–3388. 62. Yesbrendy R.E., Sanderson R.D., Gerischer G.F.R. Adhesives from autohydrolysis bagasse lignin, a renewable resourse – Рart I. The physical properties of laminates with phenolated ligninnovolacs. Part II: DSC thermal analysis of novolacresins // Holzforsch. 1992. Bd.46 (3). S. 249–255.Ссылка на английскую версию:Lignin-Polymeric CompositesLignin-Polymeric Composites Yu. N. Sazanov, Doctor of Chemistry, Professor Institute of Macromolecular Compounds of Russian Academy of Sciences, Bol'shoy pr., 31, St. Petersburg, 199004, Russia; е-mail: sazanov@hq.macro.ru
The material of the synthesis and use of polymer – lignin composites is represented. The first type includes polymer – analogous transformations which leads to the formation of different copolymers (co-condensate). To the second type one may attribute the reaction of modification of component interaction in which mainly take part the oligomeric compounds of one of reaction partner, as a result the functionality of one of components is changed and some rear cross-links forms, bringing to the fundamental property changes of initial
Keywords: lignin, synthetic polymer, polymer-analogous changes, modification, thermochemistry, thermal analysis.
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